If n is the number of solutions of the equation
$$2\cos x\left( {4\sin \left( {{\pi \over 4} + x} \right)\sin \left( {{\pi \over 4} - x} \right) - 1} \right) = 1,x \in [0,\pi ]$$ and S is the sum of all these solutions, then the ordered pair (n, S) is :

The number of solutions of the equation $${32^{{{\tan }^2}x}} + {32^{{{\sec }^2}x}} = 81,\,0 \le x \le {\pi \over 4}$$ is :

The sum of solutions of the equation

$${{\cos x} \over {1 + \sin x}} = \left| {\tan 2x} \right|$$, $$x \in \left( { - {\pi \over 2},{\pi \over 2}} \right) - \left\{ {{\pi \over 4}, - {\pi \over 4}} \right\}$$ is :