1
JEE Main 2023 (Online) 1st February Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

A solution of $$\mathrm{FeCl_3}$$ when treated with $$\mathrm{K_4[Fe(CN)_6]}$$ gives a prussium blue precipitate due to the formation of :

A
$$\mathrm{Fe[Fe(CN)_{6}]}$$
B
$$\mathrm{Fe_{4}[Fe(CN)_{6}]_{3}}$$
C
$$\mathrm{Fe_{3}[Fe(CN)_{6}]_{2}}$$
D
$$\mathrm{K[Fe_{2}(CN)_{6}]}$$
2
JEE Main 2023 (Online) 31st January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Cobalt chloride when dissolved in water forms pink colored complex $$\underline{\mathrm{X}}$$ which has octahedral geometry. This solution on treating with conc $$\mathrm{HCl}$$ forms deep blue complex, $$\underline{\mathrm{Y}}$$ which has a $$\underline{\mathrm{Z}}$$ geometry. $$\mathrm{X}, \mathrm{Y}$$ and $$\mathrm{Z}$$, respectively, are

A
$$\mathrm{X}=\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}, \mathrm{Y}=\left[\mathrm{CoCl}_{4}\right]^{2-}, \mathrm{Z}=$$ Tetrahedral
B
$$\mathrm{X}=\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}, \mathrm{Y}=\left[\mathrm{CoCl}_{6}\right]^{3-}, \mathrm{Z}=$$ Octahedral
C
$$\mathrm{X}=\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{4} \mathrm{Cl}_{2}\right]^{+}, \mathrm{Y}=\left[\mathrm{CoCl}_{4}\right]^{2-}, \mathrm{Z}=$$ Tetrahedral
D
$$\mathrm{X}=\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}, \mathrm{Y}=\left[\mathrm{CoCl}_{6}\right]^{3-}, \mathrm{Z}=$$ Octahedral
3
JEE Main 2023 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Match List I with List II:

List I (Complexes) List II (Hybridisation)
A. $\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$ I. $\mathrm{sp}^{3}$
B. $\left[\mathrm{Cu}\left(\mathrm{NH}_{3}\right)_{4}\right]^{2+}$ II. dsp$^{2}$
C. $\left[\mathrm{Fe}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}$ III. $\mathrm{sp}^{3}\mathrm{d}^{2}$
D. $\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ IV. $\mathrm{d}^{2} \mathrm{sp}^{3}$
A
A-I, B-II, C-III, D-IV
B
A-II, B-I, C-III, D-IV
C
A-I, B-II, C-IV, D-III
D
A-II, B-I, C-IV, D-III
4
JEE Main 2023 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language
The $\mathrm{Cl}-\mathrm{Co}-\mathrm{Cl}$ bond angle values in a fac- $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]$ complex is/are :
A
$90^{\circ} ~\&~ 120^{\circ}$
B
$90^{\circ}$
C
$180^{\circ}$
D
$90^{\circ} ~\& ~180^{\circ}$
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