1
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Consider the given data :

(a) $\mathrm{HCl}(\mathrm{g})+10 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{HCl} .10 \mathrm{H}_2 \mathrm{O} \Delta \mathrm{H}=-69.01 \mathrm{~kJ} \mathrm{~mol}^{-1}$

(b) $\mathrm{HCl}(\mathrm{g})+40 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{HCl} .40 \mathrm{H}_2 \mathrm{O} \Delta \mathrm{H}=-72.79 \mathrm{~kJ} \mathrm{~mol}^{-1}$

Choose the correct statement :

A
The heat of dilution for the $\mathrm{HCl}\left(\mathrm{HCl} .10 \mathrm{H}_2 \mathrm{O}\right.$ to $\left.\mathrm{HCl} .40 \mathrm{H}_2 \mathrm{O}\right)$ is $3.78 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
B
Dissolution of gas in water is an endothermic process.
C
The heat of solution depends on the amount of solvent.
D
The heat of formation of HCl solution is represented by both (a) and (b).
2
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Consider the following molecule(X).

JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 3 English

The major product formed when the given molecule $(X)$ is treated with $\mathrm{HBr}(1 \mathrm{eq})$ is :

A
JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 3 English Option 1
B
JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 3 English Option 2
C
JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 3 English Option 3
D
JEE Main 2025 (Online) 4th April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 3 English Option 4
3
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The correct order of $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ and $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ complex species based on the number of unpaired electrons present is:

A
$\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$
B
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
C
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}=\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
D
$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
4
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement (I) : Alcohols are formed when alkyl chlorides are treated with aqueous potassium hydroxide by elimination reaction.

Statement (II) : In alcoholic potassium hydroxide, alkyl chlorides form alkenes by abstracting the hydrogen from the $\beta$-carbon.

In the light of the above statements, choose the most appropriate answer from the options given below :

A
Both Statement I and Statement II are incorrect
B
Both Statement I and Statement II are correct
C
Statement I is incorrect but Statement II is correct
D
Statement I is correct but Statement II is incorrect
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