For hydrogen atom, the orbital/s with lowest energy is/are :

(A) $\mathrm{4 s}$

(B) $3 \mathrm{p}_x$

(C) $3 \mathrm{~d}_{x^2-y^2}$

(D) $3 \mathrm{~d}_{z^2}$

(E) $4 \mathrm{p}_z$

Choose the correct answer from the options given below :

Identify correct statement/s :

(A) $-\mathrm{OCH}_3$ and $-\mathrm{NHCOCH}_3$ are activating group.

(B) $\quad-\mathrm{CN}$ and -OH are meta directing group.

(C) -CN and $-\mathrm{SO}_3 \mathrm{H}$ are meta directing group.

(D) Activating groups act as ortho - and para directing groups.

(E) Halides are activating groups.

Choose the correct answer from the options given below :

Consider a complex reaction taking place in three steps with rate constants $\mathrm{k}_1, \mathrm{k}_2$ and $\mathrm{k}_3$ respectively. The overall rate constant $k$ is given by the expression $k=\sqrt{\frac{k_1 k_3}{k_2}}$. If the activation energies of the three steps are 60, 30 and $10 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, then the overall energy of activation in $\mathrm{kJ} \mathrm{mol}^{-1}$ is _________ . (Nearest integer)

The hydrocarbon $(\mathrm{X})$ with molar mass $80 \mathrm{~g} \mathrm{~mol}^{-1}$ and $90 \%$ carbon has _______ degree of unsaturation.