The density of $$3 \mathrm{M}$$ solution of $$\mathrm{NaCl}$$ is $$1.0 \mathrm{~g} \mathrm{~mL}^{-1}$$. Molality of the solution is ____________ $$\times 10^{-2} \mathrm{~m}$$. (Nearest integer).

Given: Molar mass of $$\mathrm{Na}$$ and $$\mathrm{Cl}$$ is $$23$$ and $$35.5 \mathrm{~g} \mathrm{~mol}^{-1}$$ respectively.

The value of $$\frac{1}{1 ! 50 !}+\frac{1}{3 ! 48 !}+\frac{1}{5 ! 46 !}+\ldots .+\frac{1}{49 ! 2 !}+\frac{1}{51 ! 1 !}$$ is :

Let $$S$$ be the set of all solutions of the equation $$\cos ^{-1}(2 x)-2 \cos ^{-1}\left(\sqrt{1-x^{2}}\right)=\pi, x \in\left[-\frac{1}{2}, \frac{1}{2}\right]$$. Then $$\sum_\limits{x \in S} 2 \sin ^{-1}\left(x^{2}-1\right)$$ is equal to :

Let $$R$$ be a relation on $$\mathbb{R}$$, given by $$R=\{(a, b): 3 a-3 b+\sqrt{7}$$ is an irrational number $$\}$$. Then $$R$$ is