Decreasing order of dehydration of the following alcohols is

25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M $$\mathrm{AgNO_3}$$ solution when titrated using $$\mathrm{K_2CrO_4}$$ as an indicator. What is the depression in freezing point of KCl solution of the given concentration? _________ (Nearest integer).

(Given : $$\mathrm{K_f=2.0~K~kg~mol^{-1}}$$)

Assume 1) 100% ionization and 2) density of the aqueous solution as 1 g mL$$^{-1}$$

Electrons in a cathode ray tube have been emitted with a velocity of 1000 m s$$^{-1}$$. The number of following statements which is/are $$\underline {\mathrm{true}} $$ about the emitted radiation is ____________.

Given : $$\mathrm{h=6\times10^{-34}~J~s,m_e=9\times10^{-31}~kg}$$.

(A) The de-Broglie wavelength of the electron emitted is 666.67 nm.

(B) The characteristic of electrons emitted depend upon the material of the electrodes of the cathode ray tube.

(C) The cathode rays start from cathode and move towards anode.

(D) The nature of the emitted electrons depends on the nature of the gas present in cathode ray tube.

At what pH, given half cell $$\mathrm{MnO_{4}^{-}(0.1~M)~|~Mn^{2+}(0.001~M)}$$ will have electrode potential of 1.282 V? ___________ (Nearest Integer)

Given $$\mathrm{E_{MnO_4^ - |M{n^{2 + }}}^o}=1.54~\mathrm{V},\frac{2.303\mathrm{RT}}{\mathrm{F}}=0.059\mathrm{V}$$