Sum of oxidation states of bromine in bromic acid and perbromic acid is ___________.

Number of isomeric compounds with molecular formula $$\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}$$ which (i) do not dissolve in $$\mathrm{NaOH}$$ (ii) do not dissolve in $$\mathrm{HCl}$$. (iii) do not give orange precipitate with 2,4-DNP (iv) on hydrogenation give identical compound with molecular formula $$\mathrm{C}_{9} \mathrm{H}_{12} \mathrm{O}$$ is ____________.

The total number of chiral compound/s from the following is ______________.

(i) $$\mathrm{X}(\mathrm{g}) \rightleftharpoons \mathrm{Y}(\mathrm{g})+\mathrm{Z}(\mathrm{g}) \quad \mathrm{K}_{\mathrm{p} 1}=3$$

(ii) $$\mathrm{A}(\mathrm{g}) \rightleftharpoons 2 \mathrm{~B}(\mathrm{g}) \quad \mathrm{K}_{\mathrm{p} 2}=1$$

If the degree of dissociation and initial concentration of both the reactants $$\mathrm{X}(\mathrm{g})$$ and $$\mathrm{A}(\mathrm{g})$$ are equal, then the ratio of the total pressure at equilibrium $$\left(\frac{p_{1}}{p_{2}}\right)$$ is equal to $$\mathrm{x}: 1$$. The value of $$\mathrm{x}$$ is _____________ (Nearest integer)