In KO₂, the nature of oxygen species and the oxydation state of oxygen atom are, respectively :

At a certain temperature in a $$5$$ $$L$$ vessel, 2 moles of carbon monoxide and 3 moles of chlorine were allowed to reach equilibrium according to the reaction,
         CO + Cl₂ $$\rightleftharpoons$$ COCl₂
At equilibrium, if one mole of CO is present then equilibrium constant (K_c) for the reaction is :

Following four solutions are prepared by mixing different volumes of NaOH and HCl of different concentrations, pH of which one of them will be equal to 1 ?

Given

(i)   2Fe₂O₃(s) $$ \to $$ 4Fe(s) + 3O₂(g);

$$\Delta $$_rG^o = + 1487.0 kJ mol^-1

(ii)   2CO(g) + O₂(g) $$ \to $$ 2CO₂(g);

$$\Delta $$_rG^o = $$-$$ 514.4 kJ mol^-1

Free energy change, $$\Delta $$_rG^o for the reaction

2Fe₂O₃(s) + 6CO(g) $$ \to $$ 4Fe(s) + 6CO₂(g) will be :