Consider the reaction

$$ 2 \mathrm{H}_2 \mathrm{~S}(\mathrm{~g})+3 \mathrm{O}_2(\mathrm{~g}) \rightarrow 2 \mathrm{H}_2 \mathrm{O}(\mathrm{l})+2 \mathrm{SO}_2(\mathrm{~g}) $$

The magnitude of enthalpy change for the reaction in $\mathrm{kJ} \mathrm{mol}^{-1}$ is $\_\_\_\_$ . (Nearest integer)

$$ \begin{aligned} Given:\,\,& \Delta_{\mathrm{f}} \mathrm{H}^{\ominus}\left(\mathrm{H}_2 \mathrm{~S}\right)=-20.1 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{H}^{\ominus}\left(\mathrm{H}_2 \mathrm{O}\right)=-286.0 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{f}} \mathrm{H}^{\ominus}\left(\mathrm{SO}_2\right)=-297.0 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$

Consider the reaction $\mathrm{X} \rightleftharpoons \mathrm{Y}$ at 300 K . If $\Delta \mathrm{H}^\theta$ and K are $28.40 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and $1.8 \times 10^{-7}$ at the same temperature, then the magnitude of $\Delta \mathrm{S}^\theta$ for the reaction in $\mathrm{JK}^{-1} \mathrm{~mol}^{-1}$ is $\_\_\_\_$ . (Nearest integer)

(Given : $\mathrm{R}=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}, \ln 10=2.3, \log 3=0.48, \log 2=0.30$ )

If 3.365 g of ethanol $(\mathrm{l})$ is burnt completely in a bomb calorimeter at 298.15 K , the heat produced is 99.472 kJ . The $\left|\Delta \mathrm{H}_{\mathrm{f}}{ }^{\circ}\right|$ of ethanol at 298.15 K is

$\_\_\_\_$ $\times 10^2 \mathrm{~kJ} \mathrm{~mol}^{-1}$. (Nearest integer)

Given: Standard enthalpy for combustion of graphite $=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$

Standard enthalpy of formation of water $(\mathrm{l})=-285.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$

Molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ of $\mathrm{C}, \mathrm{H}, \mathrm{O}$ are 12,1 and 16 respectively

At the transition temperature $T$, $A \rightleftharpoons B$ and $\Delta G^0 = 105 - 35 \log T$ where A and B are two states of substance X. The transition temperature in $^{\circ}\mathrm{C}$ when pressure is 1 atm is ________. (Nearest integer)