A perfect gas ( 0.1 mol ) having $\overline{\mathrm{C}}_v=1.50 \mathrm{R}$ (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is $(-)$___________$J$ (nearest integer)

[Given: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ ]

A sample of n -octane $(1.14 \mathrm{~g})$ was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is $5 \mathrm{~kJ} \mathrm{~K}^{-1}$. As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K . The magnitude of the heat of combustion of octane at constant volume is__________ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer).

Given :

$$ \begin{aligned} & \left.\Delta \mathrm{H}^{\ominus}{ }_{\text {sub }}[\mathrm{C} \text { (graphite })\right]=710 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{C}-\mathrm{H}} \mathrm{H}^{\ominus}=414 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{H}-\mathrm{H}} \mathrm{H}^{\ominus}=436 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \Delta_{\mathrm{C}}=\mathrm{C} \mathrm{H}^{\ominus}=611 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{aligned} $$

The $\Delta \mathrm{H}_{\mathrm{f}} \ominus$ for $\mathrm{CH}_2=\mathrm{CH}_2$ is_________ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer value)

Consider the following data :

Heat of formation of $\mathrm{CO}_2(\mathrm{g})=-393.5 \mathrm{~kJ} \mathrm{~mol}{ }^{-1}$

Heat of formation of $\mathrm{H}_2 \mathrm{O}(\mathrm{l})=-286.0 \mathrm{~kJ} \mathrm{~mol}{ }^{-1}$

Heat of combustion of benzene $=-3267.0 \mathrm{~kJ} \mathrm{~mol}^{-1}$

The heat of formation of benzene is __________ $\mathrm{kJ} \mathrm{mol}^{-1}$. (Nearest integer)