JEE Main 2023 (Online) 31st January Evening Shift | Thermodynamics Question 38 | Chemistry

Enthalpies of formation of $\mathrm{CCl}_{4}(\mathrm{~g}), \mathrm{H}_{2} \mathrm{O}(\mathrm{g}), \mathrm{CO}_{2}(\mathrm{~g})$ and $\mathrm{HCl}(\mathrm{g})$ are $-105,-242,-394$ and $-92 ~\mathrm{kJ}$ $\mathrm{mol}^{-1}$ respectively. The magnitude of enthalpy of the reaction given below is _________ $\mathrm{kJ} ~\mathrm{mol}^{-1}$. (nearest integer)

$\mathrm{CCl}_{4}(\mathrm{~g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \rightarrow \mathrm{CO}_{2}(\mathrm{~g})+4 \mathrm{HCl}(\mathrm{g})$

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JEE Main 2023 (Online) 31st January Morning Shift

Numerical

-1

The enthalpy change for the conversion of $$\frac{1}{2} \mathrm{Cl}_{2}(\mathrm{~g})$$ to $$\mathrm{Cl}^{-}$$(aq) is ($$-$$) ___________ $$\mathrm{kJ} \mathrm{mol}^{-1}$$ (Nearest integer)

Given : $$\Delta_{\mathrm{dis}} \mathrm{H}_{\mathrm{Cl}_{2(\mathrm{~g})}^{\theta}}^{\ominus}=240 \mathrm{~kJ} \mathrm{~mol}^{-1}, \Delta_{\mathrm{eg}} \mathrm{H}_{\mathrm{Cl_{(g)}}}^{\ominus}=-350 \mathrm{~kJ} \mathrm{~mol}^{-1}$$,

$${\mathrm{\Delta _{hyd}}H_{Cl_{(g)}^ - }^\Theta = - 380}$$ $$\mathrm{kJ~mol^{-1}}$$

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JEE Main 2023 (Online) 30th January Evening Shift

Numerical

-1

1 mole of ideal gas is allowed to expand reversibly and adiabatically from a temperature of $27^{\circ} \mathrm{C}$. The work done is $3 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The final temperature of the gas is ________ $\mathrm{K}$ (Nearest integer).

Given $\mathrm{C_V}=20 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$

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JEE Main 2023 (Online) 30th January Morning Shift

Numerical

-1

When 2 litre of ideal gas expands isothermally into vacuum to a total volume of 6 litre, the change in internal energy is ____________ J. (Nearest integer)

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