The heat of combustion of solid benzoic acid at constant volume is $$-321.30 \mathrm{~kJ}$$ at $$27^{\circ} \mathrm{C}$$. The heat of combustion at constant pressure is $$(-321.30-x \mathrm{R}) \mathrm{~kJ}$$, the value of $$x$$ is __________.

Three moles of an ideal gas are compressed isothermally from $$60 \mathrm{~L}$$ to $$20 \mathrm{~L}$$ using constant pressure of $$5 \mathrm{~atm}$$. Heat exchange $$\mathrm{Q}$$ for the compression is - _________ Lit. atm.

The enthalpy of formation of ethane $$(\mathrm{C}_2 \mathrm{H}_6)$$ from ethylene by addition of hydrogen where the bond-energies of $$\mathrm{C}-\mathrm{H}, \mathrm{C}-\mathrm{C}, \mathrm{C}=\mathrm{C}, \mathrm{H}-\mathrm{H}$$ are $$414 \mathrm{~kJ}, 347 \mathrm{~kJ}, 615 \mathrm{~kJ}$$ and $$435 \mathrm{~kJ}$$ respectively is $$-$$ __________ $$\mathrm{kJ}$$