When a $$60 \mathrm{~W}$$ electric heater is immersed in a gas for 100 s in a constant volume container with adiabatic walls, the temperature of the gas rises by $$5^{\circ} \mathrm{C}$$. The heat capacity of the given gas is ___________ $$\mathrm{J} \mathrm{K}^{-1}$$ (Nearest integer)

Consider the following data

Heat of combustion of $$\mathrm{H}_{2}(\mathrm{g})\quad\quad=-241.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

Heat of combustion of $$\mathrm{C}(\mathrm{s})\quad\quad=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

Heat of combustion of $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{l})\quad=-1234.7 \mathrm{~kJ}~{\mathrm{mol}}^{-1}$$

The heat of formation of $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{l})$$ is $$(-)$$ ___________ $$\mathrm{kJ} ~\mathrm{mol}^{-1}$$ (Nearest integer).

Consider the graph of Gibbs free energy G vs Extent of reaction. The number of statement/s from the following which are true with respect to points (a), (b) and (c) is _________

A. Reaction is spontaneous at (a) and (b)

B. Reaction is at equilibrium at point (b) and non-spontaneous at point (c)

C. Reaction is spontaneous at (a) and non-spontaneous at (c)

D. Reaction is non-spontaneous at (a) and (b)

The value of $$\log \mathrm{K}$$ for the reaction $$\mathrm{A} \rightleftharpoons \mathrm{B}$$ at $$298 \mathrm{~K}$$ is ___________. (Nearest integer)

Given: $$\Delta \mathrm{H}^{\circ}=-54.07 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

$$\Delta \mathrm{S}^{\circ}=10 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$

(Take $$2.303 \times 8.314 \times 298=5705$$ )