Given below are two statements:

Statement I : Ozonolysis followed by treatment with $\mathrm{Zn}, \mathrm{H}_2 \mathrm{O}$ of cis-2-butene gives ethanal.

Statement II : The product obtained by ozonolysis followed by treatment with $\mathrm{Zn}, \mathrm{H}_2 \mathrm{O}$ of 3, 6-dimethyloct-4-ene has no chiral carbon atom.

In the light of the above statements, choose the correct answer from the options given below

An organic compound weighing 500 mg , produced 220 mg of $\mathrm{CO}_2$, on complete combustion. The percentage composition of carbon in the compound is _________ $\%$. (nearest integer)

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ of $\mathrm{C}: 12, \mathrm{O}: 16$ )

The number of paramagnetic complexes among $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$, $\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-},\left[\mathrm{MnCl}_6\right]^{3-}$, and $\left[\mathrm{CoF}_6\right]^{3-}$, which involved $\mathrm{d}^2 \mathrm{sp}^3$ hybridization is _________.

1 Faraday electricity was passed through $\mathrm{Cu}^{2+}(1.5 \mathrm{M}, 1 \mathrm{~L}) / \mathrm{Cu}$ and 0.1 Faraday was passed through $\mathrm{Ag}^{+}(0.2 \mathrm{M}, 1 \mathrm{~L}) / \mathrm{Ag}$ electrolytic cells. After this the two cells were connected as shown below to make an electrochemical cell. The emf of the cell thus formed at 298 K is __________ mV (nearest integer)

$$\begin{aligned} \text { Given : } \mathrm{E}^{\circ} \mathrm{Cu}^{2+} / \mathrm{Cu} & =0.34 \mathrm{~V} \\\\ \mathrm{E}^{\circ} \mathrm{Ag}^{+} / \mathrm{Ag} & =0.8 \mathrm{~V} \\\\ \frac{2 \cdot 303 \mathrm{RT}}{\mathrm{~F}} & =0.06 \mathrm{~V} \end{aligned}$$