An octahedral complex having molecular composition $\mathrm{Co} \cdot 5 \mathrm{NH}_3 \cdot \mathrm{Cl}^2 . \mathrm{SO}_4$ has two isomers A and B. The solution of A gives a white precipitate with $\mathrm{AgNO}_3$ solution and the solution of B gives white precipitate with $\mathrm{BaCl}_2$ solution. The type of isomerism exhibited by the complex is,

Given below are two statements:

Statement I : Ozonolysis followed by treatment with $\mathrm{Zn}, \mathrm{H}_2 \mathrm{O}$ of cis-2-butene gives ethanal.

Statement II : The product obtained by ozonolysis followed by treatment with $\mathrm{Zn}, \mathrm{H}_2 \mathrm{O}$ of 3, 6-dimethyloct-4-ene has no chiral carbon atom.

In the light of the above statements, choose the correct answer from the options given below

An organic compound weighing 500 mg , produced 220 mg of $\mathrm{CO}_2$, on complete combustion. The percentage composition of carbon in the compound is _________ $\%$. (nearest integer)

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ of $\mathrm{C}: 12, \mathrm{O}: 16$ )

The number of paramagnetic complexes among $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$, $\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-},\left[\mathrm{MnCl}_6\right]^{3-}$, and $\left[\mathrm{CoF}_6\right]^{3-}$, which involved $\mathrm{d}^2 \mathrm{sp}^3$ hybridization is _________.