1
JEE Main 2024 (Online) 31st January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Integrated rate law equation for a first order gas phase reaction is given by (where $$\mathrm{P}_{\mathrm{i}}$$ is initial pressure and $$\mathrm{P}_{\mathrm{t}}$$ is total pressure at time $$t$$)

A
$$k=\frac{2.303}{t} \times \log \frac{P_i}{\left(2 P_i-P_t\right)}$$
B
$$\mathrm{k}=\frac{2.303}{\mathrm{t}} \times \log \frac{\left(2 \mathrm{P}_{\mathrm{i}}-\mathrm{P}_{\mathrm{t}}\right)}{\mathrm{P}_{\mathrm{i}}}$$
C
$$k=\frac{2.303}{t} \times \frac{P_i}{\left(2 P_i-P_t\right)}$$
D
$$\mathrm{k}=\frac{2.303}{\mathrm{t}} \times \log \frac{2 \mathrm{P}_{\mathrm{i}}}{\left(2 \mathrm{P}_{\mathrm{i}}-\mathrm{P}_{\mathrm{t}}\right)}$$
2
JEE Main 2024 (Online) 31st January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

For the given reaction, choose the correct expression of $$\mathrm{K}_{\mathrm{C}}$$ from the following :-

$$\mathrm{Fe}_{(\mathrm{aq})}^{3+}+\mathrm{SCN}_{(\mathrm{aq})}^{-} \rightleftharpoons(\mathrm{FeSCN})_{(\mathrm{aq})}^{2+}$$

A
$$\mathrm{K}_{\mathrm{C}}=\frac{\left[\mathrm{Fe}^{3+}\right]\left[\mathrm{SCN}^{-}\right]}{\left[\mathrm{FeSCN}^{2+}\right]}$$
B
$$\mathrm{K}_{\mathrm{C}}=\frac{\left[\mathrm{FeSCN}^{2+}\right]}{\left[\mathrm{Fe}^{3+}\right]\left[\mathrm{SCN}^{-}\right]}$$
C
$$\mathrm{K}_{\mathrm{C}}=\frac{\left[\mathrm{FeSCN}^{2+}\right]^2}{\left[\mathrm{Fe}^{3+}\right]\left[\mathrm{SCN}^{-}\right]}$$
D
$$\mathrm{K}_{\mathrm{C}}=\frac{\left[\mathrm{FeSCN}^{2+}\right]}{\left[\mathrm{Fe}^{3+}\right]^2\left[\mathrm{SCN}^{-}\right]^2}$$
3
JEE Main 2024 (Online) 31st January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals

A. have the same energy

B. have the minimum overlap

C. have same symmetry about the molecular axis

D. have different symmetry about the molecular axis

Choose the most appropriate from the options given below:

A
B, C, D only
B
A, B, C only
C
B and D only
D
A and C only
4
JEE Main 2024 (Online) 31st January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Identify correct statements from below:

A. The chromate ion is square planar.

B. Dichromates are generally prepared from chromates.

C. The green manganate ion is diamagnetic.

D. Dark green coloured $$\mathrm{K}_2 \mathrm{MnO}_4$$ disproportionates in a neutral or acidic medium to give permanganate.

E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.

Choose the correct answer from the options given below:

A
B, D, E only
B
A, B, C only
C
A, D, E only
D
B, C, D only
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