1
AIEEE 2012
MCQ (Single Correct Answer)
+4
-1
For a first order reaction, (A) $$\to$$ products, the concentration of A changes from 0.1 M to 0.025 M in 40 minutes. The rate of reaction when the concentration of A is 0.01 M is :
A
1.73 x 10–5 M/ min
B
3.47 x 10–4 M/min
C
3.47 x 10–5 M/min
D
1.73 x 10–4 M/min
2
AIEEE 2012
MCQ (Single Correct Answer)
+4
-1
Ortho–Nitrophenol is less soluble in water than p– and m– Nitrophenols because :
A
o–Nitrophenol is more volatile in steam than those of m – and p–isomers
B
o–Nitrophenol shows Intramolecular H–bonding
C
o–Nitrophenol shows Intermolecular H–bonding
D
Melting point of o–Nitrophenol is lower than those of m–and p–isomers.
3
AIEEE 2012
MCQ (Single Correct Answer)
+4
-1
In which of the following pairs the two species are not isostructural ?
A
$$CO_3^{2-}$$ and $$NO_3^-$$
B
$$PCl_4^{+}$$ and $$SiCl_4$$
C
PF5 and BrF5
D
$$AlF_6^-$$ and $$SF_6$$
4
AIEEE 2012
MCQ (Single Correct Answer)
+4
-1
The electrons identified by quantum numbers n and l :
(a) n = 4, $$l$$ = 1
(b) n = 4, $$ l$$ = 0
(c) n = 3, $$l$$ = 2
(d) n = 3, $$l$$ = 1
Can be placed in order of increasing energy as :
A
(c) < (d) < (b) < (a)
B
(d) < (b) < (c) < (a)
C
(b) < (d) < (a) < (c)
D
(a) < (c) < (b) < (d)

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