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1

AIEEE 2004

MCQ (Single Correct Answer)

+4

-1

Which of the following liquid pairs shows a positive deviation from Raoult’s law?

A

Water – hydrochloric acid

B

Acetone – chloroform

C

Water – nitric acid

D

Benzene – methanol

2

AIEEE 2004

MCQ (Single Correct Answer)

+4

-1

Which one of the following statements is false?

A

Raoult’s law states that the vapour pressure of a components over a solution is proportional to its mole fraction

B

Two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression

C

The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl₂ > KCl > CH₃COOH > sucrose

D

The osmotic pressure ($$\pi$$) = MRT, where M is the molarity of the solution

3

AIEEE 2004

MCQ (Single Correct Answer)

+4

-1

Which one of the following aqueous solutions will exhibit highest boiling point?

A

0.01 M Na₂SO₄

B

0.015 M glucose

C

0.015 M urea

D

0.01 M KNO₃

4

AIEEE 2004

MCQ (Single Correct Answer)

+4

-1

For which of the following parameters the structural isomers C₂H₅OH and CH₃OCH₃ would be expected to have the same values? (Assume ideal behaviour)

A

Heat of vaporization

B

Gaseous densities at the same temperature and pressure

C

Boiling points

D

Vapour pressure at the same temperature

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