Which one the following has largest number of isomers? (R = alkyl group, en = ethylenediamine)

The coordination number of central metal atom in a complex is determined by :

6.02 $$\times$$ 10²⁰ molecules of urea are present in 100 ml of its solution. The concentration of urea solution is
(Avogadro constant, N_A = 6.02 $$\times$$ 10²³ mol^-1)

To neutralise completely 20 mL of 0.1 M aqueous solution of phosphorous acid (H₃PO₃), the volume of 0.1 M aqueous KOH solution required is