Consider ' n ' is the number of lone pair of electrons present in the equatorial position of the most stable structure of $\mathrm{ClF}_3$. The ions from the following with ' n ' number of unpaired electrons are
A. $\mathrm{V}^{3+}$
B. $\mathrm{Ti}^{3+}$
C. $\mathrm{Cu}^{2+}$
D. $\mathrm{Ni}^{2+}$
E. $\mathrm{Ti}^{2+}$
Choose the correct answer from the options given below:
The correct order of stability of following carbocations is :

Match the List - I with List - II
| List - I (Redox Reaction) |
List - II (Type of Redox Reaction) |
||
|---|---|---|---|
| (A) | $\begin{aligned} & \mathrm{CH}_{4(\mathrm{~g})}+2 \mathrm{O}_{2(\mathrm{~g})} \xrightarrow{\Delta} \mathrm{CO}_{2(\mathrm{~g})} \\ & +2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}\end{aligned}$ | (I) | Disproportionation reaction |
| (B) | $2 \mathrm{NaH}_{(\mathrm{s})} \xrightarrow{\Delta} 2 \mathrm{Na}_{(\mathrm{s})}+\mathrm{H}_{2(\mathrm{~g})}$ | (II) | Combination reaction |
| (C) | $\begin{aligned} & \mathrm{V}_2 \mathrm{O}_{5(\mathrm{~s})}+5 \mathrm{Ca}_{(\mathrm{s})} \xrightarrow{\Delta} 2 \mathrm{~V}_{(\mathrm{s})} \\ & +5 \mathrm{CaO}_{(\mathrm{s})}\end{aligned}$ | (III) | Decomposition reaction |
| (D) | $\begin{aligned} & 2 \mathrm{H}_2 \mathrm{O}_{2(\mathrm{aq})} \stackrel{\Delta}{\longrightarrow} 2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}+ \\ & \mathrm{O}_{2(\mathrm{~g})}\end{aligned}$ | (IV) | Displacement reaction |
Choose the correct answer from the options given below:
Given below are two statements :
Statement I : 
Statement II : In
, intramolecular substitution takes place first by involving lone pair of electrons on nitrogen.
In the light of the above statements, choose the most appropriate answer from the options given below
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