The incorrect decreasing order of atomic radii is

What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non volatile solute (molar mass $256 \mathrm{~g} \mathrm{~mol}^{-1}$ ) and the decrease in freezing point is 0.40 K ?

Given below are two statements:

Statement I : D-glucose pentaacetate reacts with 2,4 -dinitrophenylhydrazine

Statement II : Starch, on heating with concentrated sulfuric acid at $100^{\circ} \mathrm{C}$ and $2-3 \mathrm{atmosphere}$ pressure produces glucose.

In the light of the above statements, choose the correct answer from the options given below

A weak acid HA has degree of dissociation x . Which option gives the correct expression of ( pH - $\mathrm{pK}_{\mathrm{a}}$)?