Which of the following linear combination of atomic orbitals will lead to formation of molecular orbitals in homonuclear diatomic molecules [internuclear axis in $z$-direction] ?
A. $2 \mathrm{p}_{\mathrm{z}}$ and $2 \mathrm{p}_{\mathrm{x}}$
B. 2 s and $2 \mathrm{p}_{\mathrm{x}}$
C. $3 d_{x y}$ and $3 d_{x^2-y^2}$
D. 2 s and $2 \mathrm{p}_{\mathrm{z}}$
E. $2 p_z$ and $3 d_{x^2-y^2}$
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Which of the following statements are NOT true about the periodic table?
A. The properties of elements are function of atomic weights.
B. The properties of elements are function of atomic numbers.
C. Elements having similar outer electronic configurations are arranged in same period.
D. An element's location reflects the quantum numbers of the last filled orbital.
E. The number of elements in a period is same as the number of atomic orbitals available in energy level that is being filled.
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One mole of the octahedral complex compound $\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}_3$ gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of $\mathrm{AgNO}_3$ solution to yield two moles of $\mathrm{AgCl}_{(\mathrm{s})}$. The structure of the complex is:
Which of the following statement is true with respect to $\mathrm{H}_2 \mathrm{O}, \mathrm{NH}_3$ and $\mathrm{CH}_4$ ?
A. The central atoms of all the molecules are $\mathrm{sp}^3$ hybridized.
B. The $\mathrm{H}-\mathrm{O}-\mathrm{H}, \mathrm{H}-\mathrm{N}-\mathrm{H}$ and $\mathrm{H}-\mathrm{C}-\mathrm{H}$ angles in the above molecules are $104.5^{\circ}, 107.5^{\circ}$ and $109.5^{\circ}$, respectively.
C. The increasing order of dipole moment is $\mathrm{CH}_4<\mathrm{NH}_3<\mathrm{H}_2 \mathrm{O}$.
D. Both $\mathrm{H}_2 \mathrm{O}$ and $\mathrm{NH}_3$ are Lewis acids and $\mathrm{CH}_4$ is a Lewis base.
E. A solution of $\mathrm{NH}_3$ in $\mathrm{H}_2 \mathrm{O}$ is basic. In this solution $\mathrm{NH}_3$ and $\mathrm{H}_2 \mathrm{O}$ act as Lowry-Bronsted acid and base respectively.
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