1
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

One mole of the octahedral complex compound $\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}_3$ gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of $\mathrm{AgNO}_3$ solution to yield two moles of $\mathrm{AgCl}_{(\mathrm{s})}$. The structure of the complex is:

A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \cdot \mathrm{Cl}_2 \cdot \mathrm{NH}_3$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \cdot 2 \mathrm{NH}_3$
D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \cdot \mathrm{Cl} \cdot \mathrm{NH}_3$
2
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which of the following statement is true with respect to $\mathrm{H}_2 \mathrm{O}, \mathrm{NH}_3$ and $\mathrm{CH}_4$ ?

A. The central atoms of all the molecules are $\mathrm{sp}^3$ hybridized.

B. The $\mathrm{H}-\mathrm{O}-\mathrm{H}, \mathrm{H}-\mathrm{N}-\mathrm{H}$ and $\mathrm{H}-\mathrm{C}-\mathrm{H}$ angles in the above molecules are $104.5^{\circ}, 107.5^{\circ}$ and $109.5^{\circ}$, respectively.

C. The increasing order of dipole moment is $\mathrm{CH}_4<\mathrm{NH}_3<\mathrm{H}_2 \mathrm{O}$.

D. Both $\mathrm{H}_2 \mathrm{O}$ and $\mathrm{NH}_3$ are Lewis acids and $\mathrm{CH}_4$ is a Lewis base.

E. A solution of $\mathrm{NH}_3$ in $\mathrm{H}_2 \mathrm{O}$ is basic. In this solution $\mathrm{NH}_3$ and $\mathrm{H}_2 \mathrm{O}$ act as Lowry-Bronsted acid and base respectively.

Choose the correct answer from the options given below:

A
A, D and E Only
B
C, D and E Only
C
A, B and C Only
D
A, B, C and E Only
3
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water. However, the reaction is spontaneous at boiling point of water. Choose the correct option.

A
Both $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ are (-ve)
B
$\Delta \mathrm{H}$ is $(+\mathrm{ve})$ but $\Delta \mathrm{S}$ is (-ve)
C
$\Delta \mathrm{H}$ is $(-\mathrm{ve})$ but $\Delta \mathrm{S}$ is (+ve)
D
Both $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ are (+ve)
4
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which of the following arrangements with respect to their reactivity in nucleophilic addition reaction is correct?

A
acetophenone $<$ benzaldehyde $<$ p-tolualdehyde $<$ p- nitrobenzaldehyde
B
acetophenone $<$ p-tolualdehyde $<$ benzaldehyde $<$ p- nitrobenzaldehyde
C
p- nitrobenzaldehyde $<$ benzaldehyde $<$ p-tolualdehyde $<$ acetophenone
D
benzaldehyde $<$ acetophenone $<$ p- nitrobenzaldehyde $<$ p-tolualdehyde
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