The standard enthalpy and standard entropy of decomposition of $\mathrm{N}_2 \mathrm{O}_4$ to $\mathrm{NO}_2$ are $55.0 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and $175.0 \mathrm{~J} / \mathrm{K} / \mathrm{mol}$ respectively. The standard free energy change for this reaction at $25^{\circ} \mathrm{C}$ in J $\mathrm{mol}^{-1}$ is ________ (Nearest integer)

3 If 1 mM solution of ethylamine produces $\mathrm{pH}=9$, then the ionization constant $\left(\mathrm{K}_{\mathrm{b}}\right)$ of ethylamine is $10^{-x}$. The value of $x$ is _________ (nearest integer).

[The degree of ionization of ethylamine can be neglected with respect to unity.]

Consider the following sequence of reactions to produce major product (A)

$\begin{aligned} & \text { Molar mass of product }(\mathrm{A}) \text { is } \mathrm{g} \mathrm{~mol}^{-1} \text {. } \\ & \text { (Given molar mass in } \mathrm{g} \mathrm{~mol}^{-1} \text { of } \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}: 16, \mathrm{Br}: 80, \mathrm{~N}: 14, \mathrm{P}: 31 \text { ) }\end{aligned}$

During " S " estimation, 160 mg of an organic compound gives 466 mg of barium sulphate. The percentage of Sulphur in the given compound is _________ %.

(Given molar mass in $\mathrm{g} \mathrm{~mol}^{-1}$ of $\mathrm{Ba}: 137, \mathrm{~S}: 32, {\mathrm{O}: 16}$)