1
JEE Main 2025 (Online) 23rd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

$\mathrm{CrCl}_3 \cdot \mathrm{xNH}_3$ can exist as a complex. 0.1 molal aqueous solution of this complex shows a depression in freezing point of $0.558^{\circ} \mathrm{C}$. Assuming $100 \%$ ionisation of this complex and coordination number of Cr is 6 , the complex will be (Given $\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )

A
$\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$
B
$\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$
C
$\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$
D
$\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]$
2
JEE Main 2025 (Online) 23rd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The major product of the following reaction is :

$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}=\mathrm{O} \xrightarrow[\text { reflux }]{\substack{\text { excess } \mathrm{HCHO} \\ \text { alkali }}}$ ?

A
JEE Main 2025 (Online) 23rd January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 21 English Option 1
B
$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{OH}$
C
JEE Main 2025 (Online) 23rd January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 21 English Option 3
D
JEE Main 2025 (Online) 23rd January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 21 English Option 4
3
JEE Main 2025 (Online) 23rd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Propane molecule on chlorination under photochemical condition gives two di-chloro products, " $x$ " and " $y$ ". Amongst " $x$ " and " $y$ ", " $x$ " is an optically active molecule. How many tri-chloro products (consider only structural isomers) will be obtained from " x " when it is further treated with chlorine under the photochemical condition?

A
4
B
2
C
3
D
5
4
JEE Main 2025 (Online) 23rd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The incorrect statement among the following is

A
$\mathrm{PH}_3$ shows lower proton affinity than $\mathrm{NH}_3$.
B
$\mathrm{SO}_2$ can act as an oxidizing agent, but not as a reducing agent.
C
$\mathrm{NO}_2$ can dimerise easily.
D
$\mathrm{PF}_3$ exists but $\mathrm{NF}_5$ does not.
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