Number of compounds with one lone pair of electrons on central atom amongst following is _________.

$$\mathrm{O}_3, \mathrm{H}_2 \mathrm{O}, \mathrm{SF}_4, \mathrm{ClF}_3, \mathrm{NH}_3, \mathrm{BrF}_5, \mathrm{XeF}_4$$

Number of compounds among the following which contain sulphur as heteroatom is ___________.

Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine

The osmotic pressure of a dilute solution is $$7 \times 10^5 \mathrm{~Pa}$$ at $$273 \mathrm{~K}$$. Osmotic pressure of the same solution at $$283 \mathrm{~K}$$ is _________ $$\times 10^4 \mathrm{Nm}^{-2}$$.

Suppose $$f(x)=\frac{\left(2^x+2^{-x}\right) \tan x \sqrt{\tan ^{-1}\left(x^2-x+1\right)}}{\left(7 x^2+3 x+1\right)^3}$$. Then the value of $$f^{\prime}(0)$$ is equal to