$\mathrm{K}_{\mathrm{a}}$ for $\mathrm{CH}_3 \mathrm{COOH}$ is $1.8 \times 10^{-5}$ and $\mathrm{K}_{\mathrm{b}}$ for $\mathrm{NH}_4 \mathrm{OH}$ is $1.8 \times 10^{-5}$. The $\mathrm{pH}$ of ammonium acetate solution will be _________.

Number of optical isomers possible for 2-chlorobutane ________.

The ratio of $\frac{{ }^{14} \mathrm{C}}{{ }^{12} \mathrm{C}}$ in a piece of wood is $\frac{1}{8}$ part that of atmosphere. If half life of ${ }^{14} \mathrm{C}$ is 5730 years, the age of wood sample is ________ years.

A bag contains 8 balls, whose colours are either white or black. 4 balls are drawn at random without replacement and it was found that 2 balls are white and other 2 balls are black. The probability that the bag contains equal number of white and black balls is :