Total number of deactivating groups in aromatic electrophilic substitution reaction among the following is _______ .

The potential for the given half cell at $298 \mathrm{~K}$ is (-) __________ $\times 10^{-2} \mathrm{~V}$

$$ \begin{aligned} & 2 \mathrm{H}_{(\mathrm{aq})}^{+}+2 \mathrm{e}^{-} \longrightarrow \mathrm{H}_2(\mathrm{~g}) \\\\ & {\left[\mathrm{H}^{+}\right]=1 \mathrm{M}, \mathrm{P}_{\mathrm{H}_2}=2 \mathrm{~atm}} \end{aligned} $$

(Given : $2.303 \mathrm{RT} / \mathrm{F}=0.06 \mathrm{~V}, \log 2=0.3$ )

Among the following oxides of p-block elements, number of oxides having amphoteric nature is ________.

$\mathrm{Cl}_2 \mathrm{O}_7, \mathrm{CO}, \mathrm{PbO}_2, \mathrm{~N}_2 \mathrm{O}, \mathrm{NO}, \mathrm{Al}_2 \mathrm{O}_3, \mathrm{SiO}_2, \mathrm{~N}_2 \mathrm{O}_5, \mathrm{SnO}_2$

Consider the following reaction :

$$ 3 \mathrm{PbCl}_2+2\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \rightarrow \mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2+6 \mathrm{NH}_4 \mathrm{Cl} $$

If $72 ~\mathrm{mmol}$ of $\mathrm{PbCl}_2$ is mixed with $50 ~\mathrm{mmol}$ of $\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4$, then the amount of $\mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2$ formed is ________ mmol (nearest integer).