Consider the following reaction approaching equilibrium at 27$$^\circ$$C and 1 atm pressure

$$\mathrm{A+B}$$ $$\mathrel{\mathop{\kern0pt\rightleftharpoons} \limits_{{k_r} = {{10}^2}}^{{k_f} = {{10}^3}}} $$ $$\mathrm{C+D}$$

The standard Gibb's energy change $$\mathrm{(\Delta_r G^\theta)}$$ at 27$$^\circ$$C is ($$-$$) ___________ kJ mol$$^{-1}$$ (Nearest integer).

(Given : $$\mathrm{R=8.3~J~K^{-1}~mol^{-1}}$$ and $$\mathrm{\ln 10=2.3}$$)

The sum of bridging carbonyls in $$\mathrm{W(CO)_6}$$ and $$\mathrm{Mn_2(CO)_{10}}$$ is ____________.

17 mg of a hydrocarbon (M.F. $$\mathrm{C_{10}H_{16}}$$) takes up 8.40 mL of the H$$_2$$ gas measured at 0$$^\circ$$C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields

The number of double bond/s present in the hydrocarbon is ___________.

Let $$\lambda \ne 0$$ be a real number. Let $$\alpha,\beta$$ be the roots of the equation $$14{x^2} - 31x + 3\lambda = 0$$ and $$\alpha,\gamma$$ be the roots of the equation $$35{x^2} - 53x + 4\lambda = 0$$. Then $${{3\alpha } \over \beta }$$ and $${{4\alpha } \over \gamma }$$ are the roots of the equation