1
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
Consider separate solutions of 0.500 M C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M KBr(aq) and 0.125 M Na3PO4(aq) at 25oC. Which statement is true about these solutions, assuming all salts to be strong electrolytes?
A
0.125 M Na3PO4(aq) has the highest osmotic pressure.
B
0.500 M C2H5OH(aq) has the highest osmotic pressure
C
They all have the same osmotic pressure
D
0.100 M Mg3(PO4)2(aq) has the highest osmotic pressure.
2
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
Resistance of 0.2 M solution of an electrolyte is 50 $$\Omega$$. The specific conductance of the solution is 1.4 S m-1. The resistance of 0.5 M solution of the same electrolyte is 280 $$\Omega$$. The molar conductivity of 0.5 M solution of the electrolyte in S m2 mol-1 is :
A
5 × 103
B
5 × 102
C
5 × 10-4
D
5 × 10-3
3
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
Given below are the half-cell reactions:

Mn2+ + 2e- $$\to$$ Mn; Eo = -1.18 V

2(Mn3+ + e- $$\to$$ Mn2+); Eo = +1.51 V

The Eo for 3Mn2+ $$\to$$ Mn + 2Mn3+ will be :
A
– 0.33 V; the reaction will not occur
B
– 0.33 V; the reaction will occur
C
– 2.69 V; the reaction will not occur
D
– 2.69 V; the reaction will occur
4
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
The equivalent conductance of NaCl at concentration C and at infinite dilution are $${\lambda _C}$$ and $${\lambda _\infty }$$, respectively. The correct relationship between $${\lambda _C}$$ and $${\lambda _\infty }$$ is given as: (where the constant B is positive)
A
$${\lambda _C} = {\lambda _\infty } + (B)C$$
B
$${\lambda _C} = {\lambda _\infty } - (B)C$$
C
$${\lambda _C} = {\lambda _\infty } - (B)\sqrt C$$
D
$${\lambda _C} = {\lambda _\infty } + (B)\sqrt C$$
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