1
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is :
A
L3 < L2 < L4 < L1
B
L1 < L2 < L4 < L3
C
L4 < L3 < L2 < L1
D
L1 < L3 < L2 < L4
2
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
For the non – stoichiometre reaction 2A + B $$\to$$ C + D, the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial Concentration (A) Initial Concentration (B) Initial rate of formation of C (mol L-1 s-1)
0.1 M 0.1 M 1.2 x 10-3
0.1 M 0.2 M 1.2 x 10-3
0.2 M 0.1 M 2.4 x 10-3
The rate law for the formation of C is:
A
$${{dc} \over {dt}} = k[A]{[B]^2}$$
B
$${{dc} \over {dt}} = k[A]$$
C
$${{dc} \over {dt}} = k[A]{[B]}$$
D
$${{dc} \over {dt}} = k[A^2]{[B]}$$
3
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
Which series of reactions correctly represents chemical relations related to iron and its compound?
A
Fe $$\buildrel {dil.\,{H_2}S{O_4}} \over \longrightarrow $$ FeSO4 $$\buildrel {{H_2}S{O_4},{O_2}} \over \longrightarrow $$ Fe2(SO4)3 $$\buildrel {heat} \over \longrightarrow $$ Fe
B
Fe $$\buildrel {{O_2} \, {, heat}} \over \longrightarrow $$ FeO $$\buildrel {dil.\,{H_2}S{O_4}} \over \longrightarrow $$ FeSO4 $$\buildrel {heat} \over \longrightarrow $$ Fe
C
Fe $$\buildrel {{Cl_2} \, {, heat}} \over \longrightarrow $$ FeCl3 $$\buildrel {heat, \, air} \over \longrightarrow $$ FeCl2 $$\buildrel {Zn} \over \longrightarrow $$ Fe
D
Fe $$\buildrel {{O_2},\,heat} \over \longrightarrow $$ Fe3O4 $$\buildrel {CO,\,{{600}^o}C} \over \longrightarrow $$ FeO $$\buildrel {CO,\,{{700}^o}C} \over \longrightarrow $$ Fe
4
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
Which one of the following properties is not shown by NO?
A
It combines with oxygen to form nitrogen dioxide
B
It’s bond order is 2.5
C
It is diamagnetic in gaseous state
D
It is a neutral oxide

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