1
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
For the non – stoichiometre reaction 2A + B $$\to$$ C + D, the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial Concentration (A) Initial Concentration (B) Initial rate of formation of C (mol L-1 s-1)
0.1 M 0.1 M 1.2 x 10-3
0.1 M 0.2 M 1.2 x 10-3
0.2 M 0.1 M 2.4 x 10-3
The rate law for the formation of C is:
A
$${{dc} \over {dt}} = k[A]{[B]^2}$$
B
$${{dc} \over {dt}} = k[A]$$
C
$${{dc} \over {dt}} = k[A]{[B]}$$
D
$${{dc} \over {dt}} = k[A^2]{[B]}$$
2
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
The equivalent conductance of NaCl at concentration C and at infinite dilution are $${\lambda _C}$$ and $${\lambda _\infty }$$, respectively. The correct relationship between $${\lambda _C}$$ and $${\lambda _\infty }$$ is given as: (where the constant B is positive)
A
$${\lambda _C} = {\lambda _\infty } + (B)C$$
B
$${\lambda _C} = {\lambda _\infty } - (B)C$$
C
$${\lambda _C} = {\lambda _\infty } - (B)\sqrt C$$
D
$${\lambda _C} = {\lambda _\infty } + (B)\sqrt C$$
3
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
The correct set of four quantum numbers for the valence elections of rubidium atom (Z= 37) is:
A
5, 1, 1, + 1/2
B
5, 1, 0, + 1/2
C
5, 0, 0, + 1/2
D
5, 0, 1, + 1/2
4
JEE Main 2014 (Offline)
MCQ (Single Correct Answer)
+4
-1
The variance of first 50 even natural numbers is
A
833
B
437
C
$${{437} \over 4}$$
D
$${{833} \over 4}$$
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