The molar conductivities $$ \wedge _{NaOAc}^o$$ and $$ \wedge _{HCl}^o$$ and at infinite dilution in water at 25^oC are 91.0 and 426.2 Scm²/mol respectively. To calculate $$ \wedge _{HOAc}^o$$ , the additional value required is

Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is 100$$\Omega $$. The conductivity of this solution is 1.29 S m^–1. Resistance of the same cell when filled with 0.2 M of the same solution is 520 $$\Omega $$, The molar conductivity of 0.02 M solution of the electrolyte will be

For a spontaneous reaction the ∆G , equilibrium constant (K) and $$E_{cell}^o$$ will be respectively

Aluminium oxide may be electrolysed at 1000^oC to furnish aluminium metal (Atomic mass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is Al³⁺ + 3e^- $$\to$$ Al^o To prepare 5.12 kg of aluminium metal by this method would require