A solution of Ni(NO₃)₂ is electrolysed between platinum electrodes using 0.1 Faraday electricity. How many mole of Ni will be deposited at the cathode?

The standard Gibbs energy for the given cell reaction in kJ mol^–1 at 298 K is :

Zn(s) + Cu²⁺ (aq) $$ \to $$ Zn²⁺ (aq) + Cu (s),

E° = 2 V at 298 K

(Faraday's constant, F = 96000 C mol^–1)

Calculate the standard cell potential in (V) of the cell in which following reaction takes place :

Fe²⁺(aq) + Ag⁺(aq) $$ \to $$ Fe³⁺(aq) + Ag (s)

Given that

$$E_{A{g^ + }/Ag}^o = xV$$

$$E_{Fe^{2+ }/Fe}^o = yV$$

$$E_{Fe^{3+ }/Fe}^o = zV$$

Given that $${E^\Theta }_{{O_2}/{H_2}O} = 1.23\,V$$ ;

$${E^\Theta }_{{S_2}O_8^{2 - }/SO_4^{2 - }} = 2.05\,V$$

$${E^\Theta }_{B{r_2}/B{r^ - }} = 1.09\,V$$

$${E^\Theta }_{A{u^{3 + }}/Au} = 1.4\,V$$

The strongest oxidizing agent is :