1
JEE Main 2019 (Online) 11th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Given the equilibrium constant:
KC of the reaction :
Cu(s) + 2Ag+ (aq) $$ \to $$ Cu2+ (aq) + 2Ag(s) is
10 $$ \times $$ 1015, calculate the E$$_{cell}^0$$ of this reaciton at 298 K
[2.303 $${{RT} \over F}$$ at 298 K = 0.059V]
KC of the reaction :
Cu(s) + 2Ag+ (aq) $$ \to $$ Cu2+ (aq) + 2Ag(s) is
10 $$ \times $$ 1015, calculate the E$$_{cell}^0$$ of this reaciton at 298 K
[2.303 $${{RT} \over F}$$ at 298 K = 0.059V]
2
JEE Main 2019 (Online) 11th January Morning Slot
MCQ (Single Correct Answer)
+4
-1
For the cell Zn(s) |Zn2+ (aq)| |Mx+ (aq)| M(s), different half cells and their standard electrode potentials are given below :
If $$E_{z{n^{2 + }}/zn}^0$$ = $$-$$ 0.76 V, which cathode will give maximum value of Eocell per electron transferred?
| Mx+ (aq)/M(s) | Au3+(aq)/Au(s) | Ag+(aq)/Ag(s) | Fe3+(aq)/Fe2+ (aq) | Fe2+(aq)/Fe(s) |
|---|---|---|---|---|
| E0Mx+/M/(V) | 1.40 | 0.80 | 0.77 | $$-$$0.44 |
If $$E_{z{n^{2 + }}/zn}^0$$ = $$-$$ 0.76 V, which cathode will give maximum value of Eocell per electron transferred?
3
JEE Main 2019 (Online) 10th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
In the cell
Pt$$\left| {\left( s \right)} \right|$$H2(g, 1 bar)$$\left| {HCl\left( {aq} \right)} \right|$$AgCl$$\left| {\left( s \right)} \right|$$Ag(s)|Pt(s)
the cell potential is 0.92 V when a 10–6 molal HCl solution is used. The standard electrode potential of (AgCl/ AgCl– ) electrode is :
$$\left\{ {} \right.$$Given, $${{2.303RT} \over F} = 0.06V$$ at $$\left. {298} \right\}$$
Pt$$\left| {\left( s \right)} \right|$$H2(g, 1 bar)$$\left| {HCl\left( {aq} \right)} \right|$$AgCl$$\left| {\left( s \right)} \right|$$Ag(s)|Pt(s)
the cell potential is 0.92 V when a 10–6 molal HCl solution is used. The standard electrode potential of (AgCl/ AgCl– ) electrode is :
$$\left\{ {} \right.$$Given, $${{2.303RT} \over F} = 0.06V$$ at $$\left. {298} \right\}$$
4
JEE Main 2019 (Online) 10th January Morning Slot
MCQ (Single Correct Answer)
+4
-1
Consider the following reduction processes :
Zn2+ + 2e– $$ \to $$ Zn(s) ; Eo = – 0.76 V
Ca2+ + 2e– $$ \to $$ Ca(s); Eo = –2.87 V
Mg2+ + 2e– $$ \to $$ Mg(s) ; Eo = – 2.36 V
Ni2 + 2e– $$ \to $$ Ni(s) ; Eo = – 0.25
The reducing power of the metals increases in the order :
Zn2+ + 2e– $$ \to $$ Zn(s) ; Eo = – 0.76 V
Ca2+ + 2e– $$ \to $$ Ca(s); Eo = –2.87 V
Mg2+ + 2e– $$ \to $$ Mg(s) ; Eo = – 2.36 V
Ni2 + 2e– $$ \to $$ Ni(s) ; Eo = – 0.25
The reducing power of the metals increases in the order :
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