For a spontaneous reaction the ∆G , equilibrium constant (K) and $$E_{cell}^o$$ will be respectively

Aluminium oxide may be electrolysed at 1000^oC to furnish aluminium metal (Atomic mass = 27 amu; 1 Faraday = 96,500 Coulombs). The cathode reaction is Al³⁺ + 3e^- $$\to$$ Al^o To prepare 5.12 kg of aluminium metal by this method would require

The standard e.m.f of a cell, involving one electron change is found to be 0.591 V at 25^oC. The equilibrium constant of the reaction is (F = 96,500 C mol^-1: R = 8.314 JK^-1 mol^-1)

Consider the following E^o values

$$E_{F{e^{3 + }}/F{e^{2 + }}}^o$$ = 0.77 V;

$$E_{S{n^{2 + }}/S{n}}^o$$ = -0.14 V

Under standard conditions the potential for the reaction

Sn(s) + 2Fe³⁺(aq) $$\to$$ 2Fe²⁺(aq) + Sn²⁺(aq) is :