The molar conductivity for electrolytes $$A$$ and $$B$$ are plotted against $$C^{3 / 2}$$ as shown below. Electrolytes $$A$$ and $$B$$ respectively are:
The emf of cell $$\mathrm{Tl}\left|\underset{(0.001 \mathrm{M})}{\mathrm{Tl}^{+}}\right| \underset{(0.01 \mathrm{M})}{\mathrm{Cu}^{2+}} \mid \mathrm{Cu}$$ is $$0.83 \mathrm{~V}$$ at $$298 \mathrm{~K}$$. It could be increased by :
The reaction;
$$\frac{1}{2} \mathrm{H}_{2(\mathrm{~g})}+\mathrm{AgCl}_{(\mathrm{s})} \rightarrow \mathrm{H}_{(\mathrm{aq})}^{+}+\mathrm{Cl}_{(\mathrm{aq})}^{-}+\mathrm{Ag}_{(\mathrm{s})}$$
occurs in which of the following galvanic cell :
Given below are two statements :
Statement (I) : Fusion of $$\mathrm{MnO}_2$$ with $$\mathrm{KOH}$$ and an oxidising agent gives dark green $$\mathrm{K}_2 \mathrm{MnO}_4$$.
Statement (II) : Manganate ion on electrolytic oxidation in alkaline medium gives permanganate ion.
In the light of the above statements, choose the correct answer from the options given below :