1
JEE Main 2024 (Online) 9th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Which out of the following is a correct equation to show change in molar conductivity with respect to concentration for a weak electrolyte, if the symbols carry their usual meaning :

A
$$\Lambda_{\mathrm{m}}-\Lambda_{\mathrm{m}}^{\circ}+\mathrm{AC}^{\frac{1}{2}}=0$$
B
$$\Lambda_{\mathrm{m}}^2 \mathrm{C}+\mathrm{K}_{\mathrm{a}} \Lambda_{\mathrm{m}}^{\mathrm{o}^2}-\mathrm{K}_{\mathrm{a}} \Lambda_{\mathrm{m}} \Lambda_{\mathrm{m}}^{\circ}=0$$
C
$$\Lambda_{\mathrm{m}}-\Lambda_{\mathrm{m}}^{\circ}-\mathrm{AC}^{\frac{1}{2}}=0$$
D
$$\Lambda_{\mathrm{m}}^2 \mathrm{C}-\mathrm{K}_{\mathrm{a}} \Lambda_{\mathrm{m}}^{\circ 2}+\mathrm{K}_{\mathrm{a}} \Lambda_{\mathrm{m}} \Lambda_{\mathrm{m}}^{\circ}=0$$
2
JEE Main 2024 (Online) 9th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

The molar conductivity for electrolytes $$A$$ and $$B$$ are plotted against $$C^{3 / 2}$$ as shown below. Electrolytes $$A$$ and $$B$$ respectively are:

JEE Main 2024 (Online) 9th April Morning Shift Chemistry - Electrochemistry Question 15 English

A
A - weak electrolyte $$\quad$$ B - weak electrolyte
B
A - weak electrolyte $$\quad$$ B - strong electrolyte
C
A - strong electrolyte $$\quad$$ B - strong electrolyte
D
A - strong electrolyte $$\quad$$ B - weak electrolyte
3
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The emf of cell $$\mathrm{Tl}\left|\underset{(0.001 \mathrm{M})}{\mathrm{Tl}^{+}}\right| \underset{(0.01 \mathrm{M})}{\mathrm{Cu}^{2+}} \mid \mathrm{Cu}$$ is $$0.83 \mathrm{~V}$$ at $$298 \mathrm{~K}$$. It could be increased by :

A
increasing concentration of $$\mathrm{Tl}^{+}$$ ions
B
increasing concentration of $$\mathrm{Cu}^{2+}$$ ions
C
increasing concentration of both $$\mathrm{Tl}^{+}$$ and $$\mathrm{Cu}^{2+}$$ ions
D
decreasing concentration of both $$\mathrm{Tl}^{+}$$ and $$\mathrm{Cu}^{2+}$$ ions
4
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The reaction;

$$\frac{1}{2} \mathrm{H}_{2(\mathrm{~g})}+\mathrm{AgCl}_{(\mathrm{s})} \rightarrow \mathrm{H}_{(\mathrm{aq})}^{+}+\mathrm{Cl}_{(\mathrm{aq})}^{-}+\mathrm{Ag}_{(\mathrm{s})}$$

occurs in which of the following galvanic cell :

A
$$\mathrm{Pt}\left|\mathrm{H}_{2(\mathrm{~g})}\right| \mathrm{HCl}_{(\text {soln.) }}\left|\mathrm{AgNO}_{3(\mathrm{aq})}\right| \mathrm{Ag}$$
B
$$\mathrm{Ag}\left|\mathrm{AgCl}_{(\mathrm{s})}\right| \mathrm{KCl}_{\text {(soln.) }}\left|\mathrm{AgNO}_{3 \text { (aq.) }}\right| \mathrm{Ag}$$
C
$$\mathrm{Pt}\left|\mathrm{H}_{2(\mathrm{~g})}\right| \mathrm{KCl}_{(\text {soln.) }}\left|\mathrm{AgCl}_{(\mathrm{s})}\right| \mathrm{Ag}$$
D
$$\mathrm{Pt}\left|\mathrm{H}_{2(\mathrm{~g})}\right| \mathrm{HCl}_{(\text {soln. })}\left|\mathrm{AgCl}_{(\mathrm{s})}\right| \mathrm{Ag}$$
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