JEE Main 2025 (Online) 29th January Evening Shift | Electrochemistry Question 2 | Chemistry

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JEE Main 2025 (Online) 29th January Evening Shift

MCQ (Single Correct Answer)

-1

$\mathrm{O}_2$ gas will be evolved as a product of electrolysis of :

(A) an aqueous solution of $\mathrm{AgNO}_3$ using silver electrodes.

(B) an aqueous solution of $\mathrm{AgNO}_3$ using platinum electrodes.

(D) a high concentration solution of $\mathrm{H}_2 \mathrm{SO}_4$ using platinum electrodes.

Choose the correct answer from the options given below :

(B) and (C) only

(B) and (D) only

(A) and (D) only

$(A)$ and $(C)$ only

JEE Main 2025 (Online) 29th January Morning Shift

MCQ (Single Correct Answer)

-1

For a Mg | Mg²⁺ (aq) || Ag⁺ (aq) | Ag the correct Nernst Equation is :

$\mathrm{E}_{\text {cell }}=\mathrm{E}_{\text {cell }}^{\mathrm{o}}-\frac{\mathrm{RT}}{2 \mathrm{~F}} \ln \frac{\left[\mathrm{Ag}^{+}\right]^2}{\left[\mathrm{Mg}^{2+}\right]}$

$\mathrm{E}_{\text {cell }}=\mathrm{E}_{\text {cell }}^{\mathrm{o}}-\frac{\mathrm{RT}}{2 \mathrm{~F}} \ln \frac{\left[\mathrm{Mg}^{2+}\right]}{\left[\mathrm{Ag}^{+}\right]}$

$\mathrm{E}_{\text {cell }}=\mathrm{E}_{\text {cell }}^{\mathrm{o}}-\frac{\mathrm{RT}}{2 \mathrm{~F}} \ln \frac{\left[\mathrm{Ag}^{+}\right]}{\left[\mathrm{Mg}^{2+}\right]}$

$\mathrm{E}_{\text {cell }}=\mathrm{E}_{\text {cell }}^{\mathrm{o}}+\frac{\mathrm{RT}}{2 \mathrm{~F}} \ln \frac{\left[\mathrm{Ag}^{+}\right]^2}{\left[\mathrm{Mg}^{2+}\right]}$

JEE Main 2025 (Online) 29th January Morning Shift

MCQ (Single Correct Answer)

-1

The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed?

Molar conductivity increases sharply with increase in concentration.

Molar conductivity decreases sharply with increase in concentration.

A small increase in molar conductivity is observed at infinite dilution.

A small decrease in molar conductivity is observed at infinite dilution.

JEE Main 2025 (Online) 29th January Morning Shift

MCQ (Single Correct Answer)

-1

The standard reduction potential values of some of the p-block ions are given below. Predict the one with the strongest oxidising capacity.

$E^o_{\text{Sn}^{4+}/\text{Sn}^{2+}} = +1.15 \text{ V}$

$E^o_{\text{Al}^{3+}/\text{Al}} = -1.66 \text{ V}$

$E^o_{\text{Pb}^{4+}/\text{Pb}^{2+}} = +1.67 \text{ V}$

$E^o_{\text{Tl}^{3+}/\text{Tl}} = +1.26 \text{ V}$

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