Match the LIST-I with LIST-II

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In a first order decomposition reaction, the time taken for the decomposition of reactant to one fourth and one eighth of its initial concentration are $t_1$ and $t_2$ (s), respectively. The ratio $t_1/t_2$ will be:

Correct statements for an element with atomic number 9 are:

A. There can be 5 electrons for which $m_s = +\frac{1}{2}$ and 4 electrons for which $m_s = -\frac{1}{2}$.

B. There is only one electron in $p_z$ orbital.

C. The last electron goes to orbital with $n = 2$ and $l = 1$.

D. The sum of angular nodes of all the atomic orbitals is 1.

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The freezing point depression of a 0.1 m aqueous solution of a monobasic weak acid HA is 0.20 °C. The dissociation constant for the acid is

Given: $K_f$(H₂O) = 1.8 K kg mol⁻¹, molality ≡ molarity