Given below are two statements :

Statement I : The rate law for the reaction $$A+B \rightarrow C$$ is rate $$(r)=k[A]^2[B]$$. When the concentration of both $$\mathrm{A}$$ and $$\mathrm{B}$$ is doubled, the reaction rate is increased "$$x$$" times.

Statement II :

The figure is showing "the variation in concentration against time plot" for a "$$y$$" order reaction.

How many compounds among the following compounds show inductive, mesomeric as well as hyperconjugation effects?

When equal volume of $$1 \mathrm{~M} \mathrm{~HCl}$$ and $$1 \mathrm{~M} \mathrm{~H}_2 \mathrm{SO}_4$$ are separately neutralised by excess volume of $$1 \mathrm{M}$$ $$\mathrm{NaOH}$$ solution. $$x$$ and $$y \mathrm{~kJ}$$ of heat is liberated respectively. The value of $$y / x$$ is __________.

The heat of solution of anhydrous $$\mathrm{CuSO}_4$$ and $$\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}$$ are $$-70 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$+12 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ respectively.

The heat of hydration of $$\mathrm{CuSO}_4$$ to $$\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}$$ is $$-x \mathrm{~kJ}$$. The value of $$x$$ is ________. (nearest integer).