When equal volume of $$1 \mathrm{~M} \mathrm{~HCl}$$ and $$1 \mathrm{~M} \mathrm{~H}_2 \mathrm{SO}_4$$ are separately neutralised by excess volume of $$1 \mathrm{M}$$ $$\mathrm{NaOH}$$ solution. $$x$$ and $$y \mathrm{~kJ}$$ of heat is liberated respectively. The value of $$y / x$$ is __________.

The heat of solution of anhydrous $$\mathrm{CuSO}_4$$ and $$\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}$$ are $$-70 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$+12 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ respectively.

The heat of hydration of $$\mathrm{CuSO}_4$$ to $$\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}$$ is $$-x \mathrm{~kJ}$$. The value of $$x$$ is ________. (nearest integer).

Molarity $$(\mathrm{M})$$ of an aqueous solution containing $$x \mathrm{~g}$$ of anhyd. $$\mathrm{CuSO}_4$$ in $$500 \mathrm{~mL}$$ solution at $$32^{\circ} \mathrm{C}$$ is $$2 \times 10^{-1} \mathrm{M}$$. Its molality will be _________ $$\times 10^{-3} \mathrm{~m}$$. (nearest integer). [Given density of the solution $$=1.25 \mathrm{~g} / \mathrm{mL}$$]

If the domain of the function $$f(x)=\sin ^{-1}\left(\frac{x-1}{2 x+3}\right)$$ is $$\mathbf{R}-(\alpha, \beta)$$, then $$12 \alpha \beta$$ is equal to :