Number of moles of $$\mathrm{H}^{+}$$ ions required by $$1 \mathrm{~mole}$$ of $$\mathrm{MnO}_4^{-}$$ to oxidise oxalate ion to $$\mathrm{CO}_2$$ is _________.

If 5 moles of an ideal gas expands from $$10 \mathrm{~L}$$ to a volume of $$100 \mathrm{~L}$$ at $$300 \mathrm{~K}$$ under isothermal and reversible condition then work, $$\mathrm{w}$$, is $$-x \mathrm{~J}$$. The value of $$x$$ is __________.

(Given R = 8.314 J K$$^{-1}$$ mol$$^{-1}$$)

The molarity of $$1 \mathrm{~L}$$ orthophosphoric acid $$\left(\mathrm{H}_3 \mathrm{PO}_4\right)$$ having $$70 \%$$ purity by weight (specific gravity $$1.54 \mathrm{~g} \mathrm{~cm}^{-3}$$) is __________ $$\mathrm{M}$$.

(Molar mass of $$\mathrm{H}_3 \mathrm{PO}_4=98 \mathrm{~g} \mathrm{~mol}^{-1}$$)

$$\mathrm{r}=\mathrm{k}[\mathrm{A}]$$ for a reaction, $$50 \%$$ of $$\mathrm{A}$$ is decomposed in 120 minutes. The time taken for $$90 \%$$ decomposition of $$\mathrm{A}$$ is _________ minutes.