Identify A and B in the following reaction sequence.
Match List I with List II
List - I (Complex ion) |
List - II (Electronic Configuration) |
||
---|---|---|---|
(A) | $$\mathrm{[Cr(H_2O)_6]^{3+}}$$ | (I) | $$t_{2 g}{ }^2 e_g^0$$ |
(B) | $$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ | (II) | $$t_{2 g}{ }^3 e_g{ }^0$$ |
(C) | $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$ | (III) | $$t_{2 g}{ }^3 e_g{ }^2$$ |
(D) | $$\left[\mathrm{V}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ | (IV) | $$t_{2 g}{ }^6 e_g^2$$ |
Choose the correct answer from the options given below:
Given below are two statements :
Statement I : Aniline reacts with con. $$\mathrm{H}_2 \mathrm{SO}_4$$, followed by heating at $$453-473 \mathrm{~K}$$ gives $$\mathrm{p}$$-aminobenzene sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
Statement II : In Friedel - Craft's alkylation and acylation reactions, aniline forms salt with the $$\mathrm{AlCl}_3$$ catalyst. Due to this, nitrogen of aniline aquires a positive charge and acts as deactivating group.
In the light of the above statements, choose the correct answer from the options given below :
A sample of $$\mathrm{CaCO}_3$$ and $$\mathrm{MgCO}_3$$ weighed $$2.21 \mathrm{~g}$$ is ignited to constant weight of $$1.152 \mathrm{~g}$$. The composition of mixture is :
(Given molar mass in $$\mathrm{g} \mathrm{~mol}^{-1} \mathrm{CaCO}_3: 100, \mathrm{MgCO}_3: 84$$)