1
JEE Main 2024 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The molecule / ion with square pyramidal shape is

A
$$\mathrm{PCl}_5$$
B
$$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$$
C
$$\mathrm{PF}_5$$
D
$$\mathrm{BrF}_5$$
2
JEE Main 2024 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements:

Statement - I: High concentration of strong nucleophilic reagent with secondary alkyl halides which do not have bulky substituents will follow $$\mathrm{S}_{\mathrm{N}}{ }^2$$ mechanism.

Statement - II: A secondary alkyl halide when treated with a large excess of ethanol follows $$\mathrm{S}_{\mathrm{N}}{ }^1$$ mechanism.

In the light of the above statements, choose the most appropriate from the options given below:

A
Both Statement I and Statement II are true.
B
Statement I is true but Statement II is false.
C
Both Statement I and Statement II are false.
D
Statement I is false but Statement II is true.
3
JEE Main 2024 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Choose the correct statements about the hydrides of group 15 elements.

A. The stability of the hydrides decreases in the order $$\mathrm{NH}_3>\mathrm{PH}_3>\mathrm{AsH}_3> \mathrm{SbH}_3>\mathrm{BiH}_3$$.

B. The reducing ability of the hydride increases in the order $$\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3 <\mathrm{SbH}_3<\mathrm{BiH}_3$$.

C. Among the hydrides, $$\mathrm{NH}_3$$ is strong reducing agent while $$\mathrm{BiH}_3$$ is mild reducing agent.

D. The basicity of the hydrides increases in the order $$\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3< \mathrm{SbH}_3<\mathrm{BiH}_3$$.

Choose the most appropriate from the options given below :

A
C and D only
B
A and D only
C
A and B only
D
B and C only
4
JEE Main 2024 (Online) 30th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: $$\mathrm{H}_2 \mathrm{Te}$$ is more acidic than $$\mathrm{H}_2 \mathrm{~S}$$.

Reason R: Bond dissociation enthalpy of $$\mathrm{H}_2 \mathrm{Te}$$ is lower than $$\mathrm{H}_2 \mathrm{~S}$$.

In the light of the above statements, choose the most appropriate from the options given below:

A
Both $$A$$ and $$R$$ are true and $$R$$ is the correct explanation of $$A$$.
B
Both $$A$$ and $$R$$ are true but $$R$$ is NOT the correct explanation of $$A$$.
C
$$A$$ is false but $$R$$ is true.
D
$$A$$ is true but $$R$$ is false.
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