The solution from the following with highest depression in freezing point/lowest freezing point is

Given below are two statements:

Statement - I: Since Fluorine is more electronegative than nitrogen, the net dipole moment of $$\mathrm{NF}_3$$ is greater than $$\mathrm{NH}_3$$.

Statement - II: In $$\mathrm{NH}_3$$, the orbital dipole due to lone pair and the dipole moment of $$\mathrm{NH}$$ bonds are in opposite direction, but in $$\mathrm{NF}_3$$ the orbital dipole due to lone pair and dipole moments of N-F bonds are in same direction.

In the light of the above statements, choose the most appropriate from the options given below:

A and B formed in the following reactions are:

$$\begin{aligned} & \mathrm{CrO}_2 \mathrm{Cl}_2+4 \mathrm{NaOH} \rightarrow \mathrm{A}+2 \mathrm{NaCl}+2 \mathrm{H}_2 \mathrm{O}, \\ & \mathrm{A}+2 \mathrm{HCl}+2 \mathrm{H}_2 \mathrm{O}_2 \rightarrow \mathrm{B}+3 \mathrm{H}_2 \mathrm{O} \end{aligned}$$

If a substance '$$A$$' dissolves in solution of a mixture of '$$B$$' and '$$C$$' with their respective number of moles as $$\mathrm{n}_{\mathrm{A}}, \mathrm{n}_{\mathrm{B}}$$ and $$\mathrm{n}_{\mathrm{C}_3}$$. Mole fraction of $$\mathrm{C}$$ in the solution is