For the given first order reaction

$$\mathrm{A} \rightarrow \mathrm{B}$$

the half life of the reaction is $$0.3010 \mathrm{~min}$$. The ratio of the initial concentration of reactant to the concentration of reactant at time $$2.0 \mathrm{~min}$$ will be equal to ___________. (Nearest integer)

The number of interhalogens from the following having square pyramidal structure is :

$$\mathrm{ClF}_{3}, \mathrm{IF}_{7}, \mathrm{BrF}_{5}, \mathrm{BrF}_{3}, \mathrm{I}_{2} \mathrm{Cl}_{6}, \mathrm{IF}_{5}, \mathrm{ClF}, \mathrm{ClF}_{5}$$

The disproportionation of $$\mathrm{MnO}_{4}^{2-}$$ in acidic medium resulted in the formation of two manganese compounds $$\mathrm{A}$$ and $$\mathrm{B}$$. If the oxidation state of $$\mathrm{Mn}$$ in $$\mathrm{B}$$ is smaller than that of A, then the spin-only magnetic moment $$(\mu)$$ value of B in BM is __________. (Nearest integer)

Total number of relatively more stable isomer(s) possible for octahedral complex $$\left[\mathrm{Cu}(\mathrm{en})_{2}(\mathrm{SCN})_{2}\right]$$ will be _________.