$$\mathrm{K}_{\mathrm{a}}$$ for butyric acid $$\left(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{COOH}\right)$$ is $$2 \times 10^{-5}$$. The $$\mathrm{pH}$$ of $$0.2 \,\mathrm{M}$$ solution of butyric acid is __________ $$\times 10^{-1}$$. (Nearest integer)

[Given $$\log 2=0.30$$]

For the given first order reaction

$$\mathrm{A} \rightarrow \mathrm{B}$$

the half life of the reaction is $$0.3010 \mathrm{~min}$$. The ratio of the initial concentration of reactant to the concentration of reactant at time $$2.0 \mathrm{~min}$$ will be equal to ___________. (Nearest integer)

The number of interhalogens from the following having square pyramidal structure is :

$$\mathrm{ClF}_{3}, \mathrm{IF}_{7}, \mathrm{BrF}_{5}, \mathrm{BrF}_{3}, \mathrm{I}_{2} \mathrm{Cl}_{6}, \mathrm{IF}_{5}, \mathrm{ClF}, \mathrm{ClF}_{5}$$

The disproportionation of $$\mathrm{MnO}_{4}^{2-}$$ in acidic medium resulted in the formation of two manganese compounds $$\mathrm{A}$$ and $$\mathrm{B}$$. If the oxidation state of $$\mathrm{Mn}$$ in $$\mathrm{B}$$ is smaller than that of A, then the spin-only magnetic moment $$(\mu)$$ value of B in BM is __________. (Nearest integer)