On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components (heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of the solution obtained by mixing 25.0g of heptane and 35 g of octane will be (molar mass of heptane = 100 g mol^–1 and of octane = 114 g mol^–1)

If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water (∆T_f), when 0.01 mol of sodium sulphate is dissolved in 1 kg of water, is (K_f = 1.86 K kg mol^–1)

The correct sequence which shows decreasing order of the ionic radii of the elements is

Ionisation energy of He⁺ is 19.6 x 10^–18 J atom^–1. The energy of the first stationary state (n = 1) of Li²⁺ is