1
AIEEE 2010
MCQ (Single Correct Answer)
+4
-1
From amongst the following alcohols the one that would react fastest with conc. HCl and anhydrous ZnCl2, is
A
2–Butanol
B
2–Methylpropan–2–ol
C
2–Methylpropanol
D
1–Butanol
2
AIEEE 2010
MCQ (Single Correct Answer)
+4
-1
A solution containing 2.675g of CoCl3. 6NH3 (molar mass = 267.5 g mol–1) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of AgNO3 to give 4.78 g of AgCl (molar mass = 143.5 g mol–1). The formula of the complex is : (At. Mass of Ag = 108 u)
A
[Co(NH3)6]Cl3
B
[CoCl2(NH3)4]Cl
C
[CoCl3(NH3)3]
D
[CoCl(NH3)5]Cl2
3
AIEEE 2010
MCQ (Single Correct Answer)
+4
-1
Which one of the following has an optical isomer ?
(en = ethylenediamine)
A
[Zn (en) (NH3)2]2+
B
[Co (en)3]3+
C
[Co (H2O)4 en]3+
D
[Zn (en)2]2+
4
AIEEE 2010
MCQ (Single Correct Answer)
+4
-1
29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl’s method and the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1 M NaOH solution for complete neutralization. The percentage of nitrogen in the compound is
A
59.0
B
47.4
C
23.7
D
29.5
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